Chem eng - Quiz W5 - Chemical bonding 1

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Môn: Chemistry for engineers (CH011IU)

Trường: Trường Đại học Quốc tế, Đại học Quốc gia Thành phố Hồ Chí Minh

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lOMoARcPSD|364906 32
QUESTION 1
1. Calculate the lattice energy for LiF(s) given the following: sublimation
energy for Li(s) +166 kJ/mol DHf for F(g) +77 kJ/mol first ionization
energy of Li(g) +520. kJ/mol electron affinity of F(g) –328 kJ/mol
enthalpy of formation of LiF(s) –617 kJ/mol
A -1052 .
kJ/mol
B 285 kJ/mol
.
C -650 kJ/mol
.
D 800 kJ/mol
.
10 points
QUESTION 2
1. A bond in which an electron pair is unequally shared by two atoms is
A nonpolar coval .
ent
B polar covalent
.
C coordinate . valent
D ionic
.
10 points
QUESTION 3
1. Which of the following statements concerning lattice energy is false?
A MgO has a larger lattice energy than NaF.
.
B Lattice energy is often defined as the change in energy that occurs when an . ionic solid is
separated into isolated ions in the gas phase.
C The lattice energy for a solid with 2+ and 2– ions should be two times that for a
.
solid with 1+ and 1– ions.
lOMoARcPSD|364906 32
D MgO has a larger lattice energy than LiF
.
10 points
QUESTION 4
1. Which of the following concerning the Coulomb's law is/are correct?
1. The energy of an ionic bond is proportional to the size of the ion charges.
2. The energy of an ionic bond is inversely proportional to the distance between
the charges.
3. The size of an ion is not important in determining the energy of an ionic bond.
A 1 only
.
B 1, 2 and
. 3
C 2 only
.
D 1 and 2
.
10 points
QUESTION 5
1. Which of the following compounds has the most ionic bonding (has the highest percentage of ionic
character)?
A CaF . 2
B LiI
.
C CsF
.
D LiF
.
10 points
QUESTION 6
1. When the cations Na+ , K+ , Rb+ , Mg2+ are combined with chloride ion in the gas phase to form ion pairs,
which pair formation releases the greatest amount of energy?
A NaCl
.
B KCl
lOMoARcPSD|364906 32
.
C RbCl
.
D MgCl
. 2
10 points
QUESTION 7
1. Which of the following compounds would be expected to have the lowest melting point?
A AlF3
.
B RbF
.
C NaF
.
D MgF
. 2
10 points
QUESTION 8
1. Chemical bonding of 02 atoms can form due to
A a lower energy than for 02 separate
. atoms
B a higher energy than for 02 separate
. atoms
C a lost energy of 02 separate atoms
.
D a gained energy of 02 separate
. atoms
10 points
QUESTION 9
1. Change in energy to form ionic compound is...
A Ionization energy
.
B Electron affinity
.
C Lattice energy
.
lOMoARcPSD|364906 32
D Dissociation
. enthalpy
10 points
QUESTION 10
1. Using bond-energy data, what is reaction energy of these reaction?
CH3OH(g) + H2S(g) --> CH3SH(g) + H2O(g)
Bond Bond energy (KJ/mol)
C-H 413
C-O 358
O-H 463
C-S 259
S-H 339
A -124 kJ/mol
.
B -25 kJ/mol
.
C 25 kJ/mol
.
D -2763 . kJ/mol
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lOMoARcPSD|364 906 32 QUESTION 1
1. Calculate the lattice energy for LiF(s) given the following: sublimation
energy for Li(s) +166 kJ/mol DHf for F(g) +77 kJ/mol first ionization
energy of Li(g) +520. kJ/mol electron affinity of F(g) –328 kJ/mol
enthalpy of formation of LiF(s) –617 kJ/mol A -1052 . kJ/mol B 285 kJ/mol . C -650 kJ/mol . D 800 kJ/mol . 10 points QUESTION 2
1. A bond in which an electron pair is unequally shared by two atoms is A nonpolar coval . ent B polar covalent . C coordinate . valent D ionic . 10 points QUESTION 3
1. Which of the following statements concerning lattice energy is false?
A MgO has a larger lattice energy than NaF. .
B Lattice energy is often defined as the change in energy that occurs when an . ionic solid is
separated into isolated ions in the gas phase.
C The lattice energy for a solid with 2+ and 2– ions should be two times that for a . solid with 1+ and 1– ions. lOMoARcPSD|364 906 32
D MgO has a larger lattice energy than LiF . 10 points QUESTION 4
1. Which of the following concerning the Coulomb's law is/are correct? 1.
The energy of an ionic bond is proportional to the size of the ion charges. 2.
The energy of an ionic bond is inversely proportional to the distance between the charges. 3.
The size of an ion is not important in determining the energy of an ionic bond. A 1 only . B 1, 2 and . 3 C 2 only . D 1 and 2 . 10 points QUESTION 5
1. Which of the following compounds has the most ionic bonding (has the highest percentage of ionic character)? A CaF . 2 B LiI . C CsF . D LiF . 10 points QUESTION 6
1. When the cations Na+ , K+ , Rb+ , Mg2+ are combined with chloride ion in the gas phase to form ion pairs,
which pair formation releases the greatest amount of energy? A NaCl . B KCl lOMoARcPSD|364 906 32 . C RbCl . D MgCl . 2 10 points QUESTION 7
1. Which of the following compounds would be expected to have the lowest melting point? A AlF3 . B RbF . C NaF . D MgF . 2 10 points QUESTION 8
1. Chemical bonding of 02 atoms can form due to
A a lower energy than for 02 separate . atoms
B a higher energy than for 02 separate . atoms
C a lost energy of 02 separate atoms .
D a gained energy of 02 separate . atoms 10 points QUESTION 9
1. Change in energy to form ionic compound is... A Ionization energy . B Electron affinity . C Lattice energy . lOMoARcPSD|364 906 32 D Dissociation . enthalpy 10 points QUESTION 10
1. Using bond-energy data, what is reaction energy of these reaction?
CH3OH(g) + H2S(g) --> CH3SH(g) + H2O(g) Bond Bond energy (KJ/mol) C-H 413 C-O 358 O-H 463 C-S 259 S-H 339 A -124 kJ/mol . B -25 kJ/mol . C 25 kJ/mol . D -2763 . kJ/mol
Document Outline

  • QUESTION 1
  • QUESTION 2
  • QUESTION 3
  • QUESTION 4
  • QUESTION 5
  • QUESTION 6
  • QUESTION 7
  • QUESTION 8
  • QUESTION 9
  • QUESTION 10